SM-4 Mercury Stack Gas Monitor

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SM-4 Mercury Stack Gas Monitor
Monitoring of Total Mercury Emissions

Mercury Instruments

  • Continuous operation
  • Sample dilution: system works with virtually any sample matrix
  • Maintenance free converter directly at stack:
    no transport of reactive mercury over distance thus minimizing mercury adsorption
  • Thermo-catalytic converter principle operating at low temperature
  • Detects elemental, ionic and bound mercury
  • Mercury speciation available (as an option)
  • Automatic calibration systems (oxidized and elemental) available
  • Automatic QAL3 as an option
  • Approved and certified by TÜV Rheinland
    Energie und Umwelt GmbH, Köln
    Report-Nr.: 936/21213740/A
    of March 26, 2012

Applications

Mercury Instruments has specially designed the SM-4 Mercury Stack Monitor to meet requirements to measure very low Hg concentrations in stack gases with a matrix containing SO2, NOx, HCl and others. Applications for the SM-4 include coal-fired plants, waste incinerators, cement kilns and all other operations with process gases that contain mercury traces in a complex matrix.

Operating Principle

The heated sampling probe is mounted at the stack. A maintenance-free ejector pump continuously draws sample gas into a dilution unit and past a heated particle filter. A critical orifice stabilizes the sample flow, thus making it independent of the pressure in the stack. The suction vacuum is continuously monitored by a pressure sensor to make operation reliable. A partial flow of the diluted sample is passed through a catalyst where the different forms of mercury contained in the sample are converted to the elemental state. This treated sample is then transported to the mercury detector through slightly heated PFA tubing , which may be tens or even some hundreds of feet away from the sampling probe. The detector uses a pre-concentration technique featuring the unique Mercury Instruments GoldTrap, one of the most sensitive and selective mercury detection devices in the market.

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SM-4: Schematic flow diagram

Thermocatalytic Reactor

The mercury present in stack gases is often elemental, but ionic and bound mercury occurs also. To measure total mercury, all these different species must be successfully detected. To this end the SM-4 uses a thermocatalytic method to convert all mercury to its elemental form. The reactor works without wet chemistry at low temperature (200 °C) and therefore assures high reliability with low demand for maintenance.

Detector

The SM-4 uses a highly sensitive detector based on the atomic absorption principle, and featuring an amalgamation unit (GoldTrap) connected upstream. The ultrapure gold surface captures the mercury which is then abruptly released when the gold trap is rapidly heated to approximately 700° C. Purified air is used as a carrier and there is no need for special carrier gases.

Sampling Probe

Mercury Instruments

The sampling probe has a key role: to extract a representative sample of gas and supply it to the sample conditioning system. All parts that come into contact with the sample are made of special material, guaranteeing a minimum memory effect. All parts are heated so no mercury is retained in the probe. An automatically backflushed filter keeps particles away from the analytical pathway of the sample. Calibration gas is introduced upstream of the sample filter. Both the dilution unit and the catalyst are integral to the sampling probe, thus ensuring minimum length for their connecting lines.

Prevention of Interferences

SO2, NOx, HCl, and VOCs all interfere with standard mercury measurement techniques. The most up-to-date mercury CEMs try to minimize this negative effect with an amalgamation step or sample dilution. Amalgamation alone, however, reaches its limit when the gold surface is affected by matrix constituents, whereas sample dilution alone may not reduce interference to tolerable levels. The SM-4 uses both sample dilution and gold trap amalgamation to completely eliminate interference.

Automatic Calibration

The SM-4 is packaged with daily calibration sources as per EPA and other national and international quality control requirements. It is available with built-in span calibration sources for elemental or ionic mercury and can also perform a baseline check automatically. The latest development is a calibration gas generator that produces ionic mercury reference gas and can be integrated into the SM-4 system for automatic operation. Quality assurance during operation as required by the European Regulation EN 14181 (QUAL3) can be performed automatically.

Features and Benefits of the SM-4

  • Dry thermocatalytic method: no need for reagents, water refills or solid reagent cartridge replacements.
  • Sample dilution eliminates interference from matrix gases such as SO2, NOx, and HCl and
    produces a large measuring range.
  • Approved according to European regulations, for USA: RATA tests passed with excellent result
  • No liquid waste or condensate is generated
  • Extreme high sensitivity: low measuring range is 0.05 µg/m³
  • Automatic cleaning of particulate filter
  • Fast response: t(90) time typically 180 sec
  • Sample line length up to 300 feet
  • ionic calibration gas generator as an option allows automatic quality assurance (QAL3)
  • Option to install an elemental mercury calibration gas generator,
    NIST traceable, inside the analyzer cabinet
  • Very low maintenance

System components

  • Sample conditioning system with detachable sampling probe
  • Heated bundle containing sample line, air supply line, calibration gas feed line
  • Probe controller module
  • Analyzer cabinet with detector and calibrator (option)

Mercury Instruments

 SM-4 Technical Specifications

Principle of measurement:

Sample dilution, thermo catalytic converter,
atomic absorption detector with Gold Trap

Converter:

Low temperature type (200 °C); directly at stack

Detection principle:

Cold Vapor Atom Absorption Spectrometry (CVAAS), wavelength 253.7 nm

Measured component:

total mercury (oxidised and elemental speciation optionally)

Measuring range:

0.05 µg/m³ to 500 µg/m³ Hg (up to 1000 µg/m³ as an option)

Detection limit (detector):

0.0001 µg/m³ (detector); <0.01 µg/m³ (system)

Response time:

180 – 360 sec

Max. Sample gas temperature:

250 °C (482 °F)

Ambient temperature range allowed:

-5 °C to 40 °C (23 °F to 104 °F)

Sample line length:

Up to 30 m (100 feet); up to 100 m (300 feet) optionally

Signal output:

4-20 mA (500 Ohms); RS232; modbus RTU/RS485 (option) ; ethernet (option)

Status output:

3 x pairs of relay contacts (dry contacts)

Remote access:

Modem and SM-4 communication software (option)

Dimensions:

Analyzer cabinet: 161 x 80 x 60 cm (63.6”x 32”x 23.6”) HxWxD
Probe: 36 x 36 x 66 cm (14.2”x 14.2”x 26”) HxWxD
Probe controller: 48 x 44 x 27 cm (19”x 17” x 11”) HxWxD

Weight:

Analyzer (including automatic calibrator): 130 kg (285 lbs)
Probe controller: 14 kg (30 lbs)
Converter unit: 28 kg (62 lbs)

Air consumption:

6 bar (85 PSI); 16 l/min approx.

Calibration/span check:

Automatically, with an integrated calibration gas generator (option). A heated fitting is installed at the probe for feed of externally provided calibration gases

Certifications:

Conforms to US EPA 40CFR60 PS-12A Mercury CEMS; conforms to EN 15267 (European regulation); Approved and certified by TÜV Rheinland Energie und Umwelt GmbH, Köln, Report-Nr.: 936/21213740/A of March 26, 2012

 

 

 Mercury Instruments

As a leading supplier of high precision analytical equipment, we strive at all times to offer top quality solutions. Our products are manufactured according to the ISO 9001 quality regulations.